Isolation, structure determination, and biological activity of a novel alkaloid, perophoramidine, from the Philippine ascidian Perophora namei
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Date
2002-09-12
Authors
Verbitski, Sheryl M.
Mayne, Charles L.
Davis, Rohan A.
Concepcion, Gisela
Ireland, Chris M.
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American Chemical Society (ACS)
Abstract
Chemical investigation of the Philippine ascidian Perophora namei has resulted in the isolation of a novel polycyclic alkaloid, perophoramidine (1). The structure of 1 was determined by the interpretation of 1D/2D NMR and MS data. Dehalogenation of perophoramidine (1) by ammonium formate catalyzed transfer hydrogenation confirmed the type and number of halogen atoms present in 1.
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Citation
Verbitski, S. M., Mayne, C. L., Davis, R. A., Concepcion, G. P., & Ireland, C. M. (2002). Isolation, structure determination, and biological activity of a novel alkaloid, perophoramidine, from the Philippine ascidian Perophora namei. The Journal of Organic Chemistry, 67(20), 7124–7126. https://doi.org/10.1021/jo026012f